Product ID:DART 214
MSDS Date:11/04/1989
FSC:6850
NIIN:00N011522
MSDS Number: BJFHB

MADISON CHEMICAL CO,INC

STATE ROAD 62
MADISON, IN 47250
US

Emergency Phone: 812-273-6000 WK DAYS;812 (SUP DATA)

Info Phone: 812-273-6000 WEEK DAYS

Preparer: STEVEN T HALE

Cage: 60142

MADISON CHEMICAL CO INC

125 MADISON, IN 47250 US

Cage: 60142

NICKEL NITRATE.ACGIH TLV AS STATED ON NOTICE OF INTENDED

CAS: 13138-45-9

RTECS: QR7200000

Fraction By Weight: 0.7% MAX

OSHA PEL 0.1 MG(NI)/M3

ACGIH TLV: 0.05 MG(NI)/M3

PHOSPHORIC ACID (SARA III)

CAS: 7664-38-2

RTECS: TB6300000

Fraction By Weight: 17% MAX

OSHA PEL 1 MG/M3/3 STEL

ACGIH TLV: 1 MG/M3/3 STEL; 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

BORIC ACID

CAS: 10043-35-3

RTECS: ED4550000

Fraction By Weight: 2%

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:N/K
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:OVEREXPOSURE TO NICKEL COMPOUNDS MAY
CAUSE DERMATITIS.
Explanation of Carcinogenicity:NICKEL & NI CMPDS:SUFFICIENT EVID FOR
CARC IN HUMANS/ANIMALS (IARC,1987).ACGIH A1=KNOWN HUMAN CARC
(1990).(SEE SUPP)
Effects of Overexposure:EYES:IRRITATION.SKIN:IRRITATION.PRLNG/RPTD
OVEREXP MAY CAUSE BURNS.POSS DERMAT.BORIC ACID NOT ABSORBED FROM
INTACT SKIN.BROKEN SKIN/INGEST/INHAL:BORIC ACID INGESTION OR
PRLNG/RTD CONTACT W/ MUCOUS MEM BRANES OR BROKEN SKIN AFFECTS
CENTRAL NERVOUS SYSTEM,MAY RESULT IN DEPRESSION OF
CIRCULATION,VOMITING,DIARRHEA,COMA.
Medical Cond Aggravated by Exposure:N/K

First Aid:EYES:IMMED FLUSH W/ LARGE QUANTITIES OF COOL WATER
CONTINUOUSLY FOR AT LEAST 15 MIN.CALL MD.SKIN:IMMED FLUSH W/ LARGE
QUANTITIES OF COOL WATER CONTINUOUSLY FOR AT LEAST 15 MIN.CALL
MD.REMOVE CONTAM CL OTHING/SHOES.INGESTION:DO NOT INDUCE
VOMITING.GIVE WATER.NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON.CALL MD.INHALATION:REMOVE SUBJECT TO FRESH AIR.IF SYMPTOMS
PRESENT,GET MEDICAL ATTENTION.

Flash Point Method:TOC
Flash Point:NONE TO BOILING
Extinguishing Media:AS APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:HAZARDOUS DECOMPOSITION
PRODUCTS:PHOSPHORUS OXIDES,NITROGEN OXIDES,BORON OXIDES.

Spill Release Procedures:CONTAIN LIQUID SPILLS WITH SAND AND ABSORB ON
SODA ASH.DISPOSE WITH SOLID WASTES.
Neutralizing Agent:N/K

Handling and Storage Precautions:NORMAL FOR ACIDS.AVOID INGESTION AND
PHYSICAL CONTACT WITH PRODUCT,SOLUTIONS,VAPORS.
Other Precautions:FOR INDUSTRIAL USE ONLY.KEEP OUT OF REACH OF
CHILDREN.MAY BE HARMFUL IF SWALLOWED.CONTAINS PHOSPHORIC ACID,BORIC
ACID,AND NICKEL NITRATE.

Respiratory Protection:USE NIOSH/MSHA APPROVED INORGANIC ACID VAPOR
RESPIRATOR FOR AREAS WHERE AIRBORNE EXPOSURE IS EXCESSIVE.
Ventilation:USE GOOD VENTILATION.LOCAL EXHAUST IS RECOMMENDED IF TLV'S
ARE EXCEEDED.
Protective Gloves:IMPERMEABLE TYPE
Eye Protection:GOGGLES AND FACESHIELD NECESSARY.
Other Protective Equipment:RUBBER APRON & BOOTS REQUIRED,OTHER EQUIP AS
REQUIRED TO AVOID CONTACT.EYEWASH FACILITY & EMERGENCY SHOWER.
Work Hygienic Practices:WASH CONTAM CLOTHING & SHOES THOROUGHLY IN SOAP
& WATER;RINSE REPEATEDLY IN CLEAN WATER & DRY BEFORE REUSE.
Supplemental Safety and Health
MFR EMER TEL NO:265-2703,812-273-6213 EVENINGS & WEEKENDS.ROUTES OF
ENTRY:EYES,MUCOUS MEMBRANES (MFR);INGESTION/INHALATION .PH:0.5-0.8
(100%);2.4-2.6 (1% BY VOLUME).EXPLAN OF CARCIN:NI & CERTAIN NI
COMPOUNDS:SUSPECTED HUMAN CARCINOGEN/KNOWN ANIMAL CARCINOGEN
(NTP,1989).KNOWN TO CAUSE CANCER (CAL PROP 65,1989).

Boiling Pt:B.P. Text:230F,110C
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Spec Gravity:1.36 (WATER=1)
pH:SUP DA
Evaporation Rate & Reference:1.0 (WATER=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR,GREEN LIQUID WITH A MILD ODOR.

Stability Indicator/Materials to Avoid:YES
ALKALINE MATERIALS,REDUCING AGENTS.
Hazardous Decomposition Products:PHOSPHORUS OXIDES,NITROGEN
OXIDES,BORON OXIDES.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE W/ FEDERAL,STATE
& LOCAL REGULATIONS .NORMAL FOR ACIDIC WASTES CONTAINING
PHOSPHATES,ZINC/NICKEL CMPDS.MAY REQUIRE PH ADJUSTMENT FOR
NEUTRALIZATION.PHOSPHORIC ACID ,NICKEL NITRATE:SARA TITLE III SECT
313:LISTED.

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